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Address: Department of Chemistry, Gottwald Center for the Sciences, C-108 The University of Richmond, Richmond, VA (o) (f)

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Curriculum Vitae For WILLIAM H. MYERS Address: Department of Chemistry, Gottwald Center for the Sciences, C-108 The University of Richmond, Richmond, VA (o) (f) address:
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Curriculum Vitae For WILLIAM H. MYERS Address: Department of Chemistry, Gottwald Center for the Sciences, C-108 The University of Richmond, Richmond, VA (o) (f) address: wmyers(at)richmond.edu Home page: facultystaff.richmond.edu/~wmyers/ Education: Postdoctoral Fellow, , Ohio State University, Columbus, Ohio; Advisor: Prof. Devon W. Meek, research in coordination chemistry PhD, 1972, University of Florida, Gainesville, Florida: Inorganic Chemistry. Dissertation Title: Trends in the Proton NMR Spectra of Some Amine-Haloboranes: Steric Effects ; Advisor: Prof. George E. Ryschkewitsch BA (magna cum laude), 1967, Houston Baptist College, Houston, Texas: Majors in Chemistry, Mathematics, and Physics; special study in X-ray crystallography at the University of Arkansas, Fayetteville, summer, 1966 (Mentor: Prof. A.W. Cordes), and in electron microscopy at Argonne National Laboratory, Chicago, IL, spring, Employment and Professional Positions Held: 1993-present Professor of Chemistry, Univ of Richmond, Richmond, VA 1991-present Visiting Research Professor/Visiting Scholar, Univ. of Virginia, Charlottesville, VA Chair, Department of Chemistry, Univ of Richmond, Richmond, VA 2000, spring semester Visiting Research Professor, University of Virginia, Charlottesville, VA, metal-mediated organic synthesis with Prof. W. Dean Harman (on sabbatical leave from the University of Richmond) Visiting Research Associate Professor, University of Virginia, Charlottesville, VA, metal-mediated organic synthesis with Prof. W. Dean Harman (on sabbatical leave from the University of Richmond) Associate Professor of Chemistry, University of Richmond, Richmond, VA Research Chemist, organometallics and catalysis, Ethyl Corporation, Research and Development, Baton Rouge, LA (on sabbatical leave from the University of Richmond) Assistant Professor of Chemistry, Univ. of Richmond, Richmond, VA; tenured in Instructor of Chemistry, University of Florida, Gainesville, FL 1967, summer Research Chemist, chromatography and mass spectroscopy of crude oils, Esso Production Research, Houston, TX. Military: US Army Reserves, Chemical Corps ; Honorable Discharge with rank of Captain, 1981 Honors and Awards: Visiting Research Professor/Visiting Scholar, Univ. of Virginia, Charlottesville, VA (1991-present) Professor of the Year, from the the U.Richmond Chapter of Omicron Delta Kappa (ODK) (2012) Spotlight Award, from the U.Richmond Dept of Theatre & Dance for support of the Arts (2011) Advisor Excellence Award, Univ of Richmond (2008) Pioneer Award for Excellence in Teaching, Learning, and Technology, Univ of Richmond (2000) Distinguished Educator Award, University of Richmond (1987) Omicron Delta Kappa, Alumni Member, Houston Baptist University (1986) Sigma Xi, Science Honorary, University of Richmond (1975) Gamma Sigma Epsilon (now Sigma Pi Pi), Chemistry Honorary, University of Richmond (1974) Phi Beta Kappa, University of Florida (1972) National Aeronautics and Space Administration Traineeship, University of Florida ( ) National Science Foundation Summer Fellowship, University of Florida (1969) National Science Foundation Traineeship, University of Florida ( ; renewed in 1968, but declined because of military obligations) President's Award to Most Outstanding Male Student, Houston Baptist College (1965) Curriculum Vitae William H. Myers p.2 Major University Assignments since 1982: Advisory Committee Sophomore Scholars-in-Residence (SSIR) (2007-present) Health Professions Advisory Committee ( , ; chair, ) University Marshals ( ); service as the University Marshal ( ) Faculty Representative to UR Board of Trustees, Academic & Enrollment Mgt ( ) Richmond Scholars Selection Committee--Boatwright (2012), Science (2010, ) A&S Summer Fellowship Selection Committee--Grainger (2012) Hearing Board, U.Richmond Student Affairs ( ) Advisory Board The Center for Teaching, Learning, and Technology ( ) Chair, Department of Chemistry ( ) Faculty Advisory Committee, SACS Reaccrediation Quality Enhancement Plan/Sophomore Scholars-in-Residence Program (member, ) HHMI Proposal Planning Group Princeton Univ visit/evaluate ID science courses (fall, 2007) Ad Hoc Review Committee, Tenure and Promotion Policy & Procedure ( ) Ethyl & Albemarle Science Scholars Committee, chair ( ); faculty advisor for Ethyl Scholars ( ; ) Center for Baptist Heritage and Study, Faculty Representative ( ) Provost Search Committee, member (2001) Planning and Priorities Committee (SACS Reaccredidation) Task Force on Student Futures ( ) University of Richmond Faculty Council ( ) Phi Beta Kappa, chair, committee on nomination of members-in-course ( ) Planning and Priorities Committee Task Force on the Co-Curricular Experience ( ) University Strategic Planning Committee ( ) Coordinate College Committee and Coed Housing Committee ( ) Jepson School of Leadership Studies: Planning Committee and Dean Search Committee ( ) Science Librarian Search Committee, chemistry representative ( ) University Self Study, Committee on Organization and Administration, secretary and chair of two subcommittees ( ) University President Search Committee ( ) Graduate Council, chemistry representative ( ) Faculty Advisory Panel/Faculty Council ( ) University Hearing Board ( ) Cornerstones for the Future Fund-raising Campaign, Faculty Committee ( ) University Research Committee ( ) Westhampton College Faculty Advisor ( ) University Provost Search Committee ( ) University Governance Study, Task Force on University College ( ) Curriculum Vitae William H. Myers p.3 Professional Publications: (undergraduate co-authors starred = *) xx. A.W. Lankenau*, D.A. Iovan*, J.A. Pienkos, R.J. Salomon, S. Wang, W.H. Myers, W.D. Harman Enantio-Enrichment of a Tungsten Dearomatizing Agent Utilizing Dibenzoyl Tartaric Acid in preparation xx. S.A. Burgess, T. Bolaño, T.B. Gunnoe, M. Sabat, W.H. Myers Synthesis of Rh(III) Anilido, Hydroxide and Methoxide Complexes submitted to Eur J of Inorg Chem 62. B.L. MacLeod, J.A. Pienkos, J.T. Myers, M. Sabat, W.H. Myers, and W.D. Harman Synthesis of Tetrahydroindoline Derivatives Promoted by a Tungsten π -Base Organometallics, 2014, 33, J.A. Pienkos, A.T. Knisely*, B.L. MacLeod, J.T. Myers, P.J. Shivokevich, V. Teran, M. Sabat, W.H. Myers, and W.D. Harman Double Protonation of Amino-Substituted Pyridine and Pyrimidine Tungsten Complexes: Friedel-Crafts-like Coupling to Aromatic Heterocycles Organometallics, 2014, 33, S.A. Burgess, E.E. Joslin, T. B. Gunnoe, T.R. Cundari, M. Sabat, and W.H. Myers Hydrophenylation of Ethylene using a Cationic Ru(II) Catalyst: Comparison to a Neutral Ru(II) Catalyst Chemical Science (RSC), 2014, 5, E.E. Joslin, B. Quillian, T.B. Gunnoe, T.R. Cundari, M. Sabat, W.H. Myers C-H Activation of Pyrazolyl Ligands by Ru(II) Inorganic Chemistry, 2014, 53, May 31, S.A. Burgess, D. Devarajan, T. Bolaño, D.H. Ess, T.B. Gunnoe, M. Sabat, and W.H. Myers 1,2- Addition of Dihydrogen across Rh(III) OMe Bonds Inorganic Chemistry, 2014, 53, J.A. Pienkos, A.T. Knisely*, B.K. Liebov, V. Teran, V.E. Zottig, M. Sabat, W.H. Myers, and W.D. Harman Tungsten-Mediated Selective Ring Opening of Vinylcyclopropanes Organometallics, 2014, 33, May 31, J.A. Pienkos, V.E. Zottig, D.A. Iovan*, M. Li*, D.P. Harrison, M. Sabat, L.J. Strausberg, V.A. Teran, W.H. Myers, and W.D. Harman Friedel Crafts Ring-Coupling Reactions Promoted by Tungsten Dearomatization Agent Organometallics, 2013, 32, L.J. Strausberg, M. Li, D.P. Harrison, W.H. Myers, M. Sabat, and W.D. Harman Exploiting the o- Quinodimethane Nature of Naphthalene: Cycloaddition Reactions with Dihapto-coordinated Tungsten Naphthalene Complexes Organometallics, 2013, 32, B. Quillian, E.E. Joslin, T.B. Gunnoe, M. Sabat, W.H. Myers 2,2,2-Tris(pyrazolyl)ethoxide (Ep OX ) Ruthenium (II) Complexes, (Ep OX )RuCl(L)(L ): Synthesis, Structure and Reactivity Inorg. Chem., 2013, 52, M.J. Pouy, S.A. Delp, J. Uddin, V.M. Ramdeen, N.A. Cochrane, G.C. Fortman, T.B. Gunnoe, T.R. Cundari, M. Sabat, and W.H. Myers Intramolecular Hydroalkoxylation and Hydroamination of Alkynes Catalyzed by Cu(I) Complexes Supported by N-Heterocyclic Carbene Ligands ACS Catalysis, 2012, 2, E.E. Joslin, C.L. McMullin, T.B. Gunnoe, T.R. Cundari, M. Sabat, W.H. Myers Catalytic Hydroarylation of Ethylene Using TpRu(L)(NCMe)Ph (L = 2,6,7-Trioxa-1- phosphabicyclo[2,2,1]heptane): Comparison to TpRu(L')(NCMe)Ph Systems [L' = CO, PMe 3, P(pyr)3 or P(OCH 2 ) 3 CEt)] Organometallics 2012, 31, May 31, E.E. Joslin, C.L. McMullen, T.B. Gunnoe, T.R. Cundari, M. Sabat, W.H. Myers Coordination Chemistry of 4-methyl-2,6,7-trioxa-1-phosphabicyclo[2,2,1]heptane: Preparation and Characterization of Ru(II) Complexes Inorganic Chemistry, 2012, 51, Curriculum Vitae William H. Myers p D.P. Harrison, D.A. Iovan*, W.H. Myers, M. Sabat, S. Wang, V.E. Zottig, W.D. Harman [4+2] Cyclocondensation Reactions with Tungsten Dihydropyridine Complexes and the Generation of Tri- and Tetrasubstituted Piperidines Journal of the American Chemical Society, 2011, 133, May 31, D.P. Harrison, A.C. Nichols-Nielander*, V.E. Zottig, L.J. Strausberg, R.J. Salomon, C.O. Trindle, M. Sabat, T.B. Gunnoe, D.A. Iovan*, W.H. Myers, and W.D. Harman Hyper-Distorted Tungsten Allyl Complexes and their Stereoselective Deprotonation to Form Dihapto-Coordinated Dienes Organometallics, 2011, 30, J.P. Burke, M. Sabat, W.H. Myers, J.J. Chruma, Unexpected exo selectivity for an intramolecular Diels-Alder reaction involving a doubly-activated δ-pentenolide dienophile Tetrahedron: Asymmetry, 2011, 22, D.P. Harrison, M. Sabat, W.H. Myers, W.D. Harman, Polarization of the Pyridine Ring: Highly Functionalized Piperidines from Tungsten-Pyridine Complex Journal of the American Chemical Society, 2010, 132, J.A. Marshall, C.A. Griot, H.R. Chobanian, W.H. Myers, Synthesis of a Lactone Diastereomeric of the Cembranolide Uprolide D Organic Letters, 2010, 12, May 31, V.E. Zottig, M.A. Todd, A.C. Nichols-Neilander*, D.P. Harrison, M. Sabat, W.H. Myers, W.D. Harman, Epoxidation, Cyclopropanation, and Electrophilic Addition Reactions at the metaposition of Phenol and meta-cresol Organometallics, 2010, 29, J.P. Burke, M. Sabat, D.A. Iovan*, W.H. Myers and J.J. Chruma Exploring the Original Proposed Biosynthesis of (+)-Symbioimine: Remote Exocyclic Stereocontrol in a Type I IMDA Reaction Organic Letters, 2010, 12, D.P. Harrison, G.W. Kosturko, V.M. Ramdeen, A.C. Nichols-Nielander*, M. Sabat, W.H. Myers, W.D. Harman Tungsten-Promoted Pyridine Ring Scission: The Selective Formation of η 2 - Cyanine and η 2 -Merocyanine Complexes and their derivatives Organometallics, 2010, 29, R.J. Salomon, M.A. Todd, M. Sabat, W.H. Myers, W.D. Harman, Single and Double Electrophilic Addition Reactions to the Aniline Ring Promoted by a Tungsten π-base Organometallics, 2010, 29, K.D. Welch, D.P. Harrison, M. Sabat, E.Z. Hejazi*, B.T. Parr*, M.G. Fanelli*, N.A. Gianfrancesco*, D.S. Nagra*, W.H. Myers, W.D. Harman Michael Aldol Ring Closures with Dihapto-Coordinated Pyrrole Complexes and the Synthesis of Tetrahydroindole Cores Organometallics, 2009, 28, D.P. Harrison, V.E. Zottig, G.W. Kosturko, K.D. Welch, W.H. Myers, W.D. Harman Stereo- and Regioselective Nucleophilic Addition to Dihapto-Coordinated Pyridine Complexes Organometallics, 2009, 28, R. J. Salomon, E.C. Lis, M.U. Kasbekar*, K.C. Bassett, W.H. Myers, C.O. Trindle, M. Sabat, W.D. Harman Stereoelectronic Effects in Dihapto-coordinated Complexes of TpW(NO)(PMe 3 ) and their Manifestation in Diels-Alder Cycloaddition of Arenes Organometallics, 2009, 28, May 31, G.W. Kosturko, D.P. Harrison, M. Sabat, W.H. Myers, W.D. Harman Selectfluor Mediated Dialkoxylation of Tungsten η 2 -pyridinium Complexes Organometallics, 2009, 28, D.P. Harrison, K.D. Welch, A.C. Nichols-Nielander*, M. Sabat, W.H. Myers, W.D. Harman, An Efficient Synthesis of an η 2 -Pyridine Complex and a Preliminary Investigation of the Bound Heterocycle's Reactivity Journal of the American Chemical Society, 2008, 130, Curriculum Vitae William H. Myers p E. Lis, R. Salomon, M. Sabat, W.H. Myers, W.D. Harman, Synthesis of 1-Oxadecalins from Anisole Promoted by Tungsten Journal of the American Chemical Society, 2008, 130, G.W. Kosturko, P.M. Graham, W.H. Myers, T.M. Smith, M. Sabat, and W.D. Harman Tungsten- Promoted Diels-Alder Cycloaddition of Pyridines: Dearomatization of 2,6-Dimethoxypyridine Generates a Potent 2-Azadiene Synthon Organometallics, 2008, 27, May 31, M.A. Todd, M. Sabat, W.H. Myers, T.M. Smith, W.D. Harman, Stereoselective Umpolung Tandem Addition of Heteroatoms to Phenol Journal of the American Chemical Society, 2008, 130, M.A. Todd, M. Sabat, W.H. Myers, W.D. Harman [2+2] Cycloaddition Reactions with a Tungsten- Stabilized 2H-Phenol Journal of the American Chemical Society, 2007, 129, May 31, K.D. Welch, E.C. Lis, Jr., W. Liu, D.P. Harrison, R.J. Salomon, W.H. Myers, and W.D. Harman Large-Scale Syntheses of Several Synthons to the Dearomatization Agent {TpW(NO)(PMe 3 )} and Convenient Spectroscopic Tools for Product Analysis Organometallics, 2007, 26, W. Liu, K. Welch, C.O. Trindle, M. Sabat, W.H. Myers, and W.D. Harman Facile Intermolecular Aryl-F Bond Cleavage in the Presence of Aryl C-H bonds: Is the 2-Arene Intermediate Bypassed? Organometallics, 2007, 26, D.A. Delafuente, G.W. Kosturko, P.M. Graham, W.H. Harman*, W.H. Myers, Y. Surendranath*, R.C. Klet*, C.O. Trindle, M. Sabat, and W.D. Harman Isomerization Dynamics and Control of the η 2 /N Equilibrium for Pyridine Complexes Journal of the American Chemical Society, 2007, 129, Y. Surendranath*, W.H. Myers, and W.D. Harman Tungsten Promoted Dearomatization of Heterocycles: Uncovering the Latent 2-Azadiene Character of Pyrimidines Organometallics, 2006, 25, K.D. Welch, P.L. Smith, A.P. Keller*, W.H. Myers, M. Sabat. W.D. Harman. Osmium(II)-, Rhenium(I)-, and Tungsten(0)-Promoted Dipolar Cycloaddition Reactions with Pyrroles: Exploiting the Azomethine Ylide Character of this Heterocycle Organometallics, 2006, 25, E. Lis, W. Liu, M.A. Todd, W.H. Myers, D.A. Delafuente, Y. Lin*, M. Sabat, C. Mocella, W.D. Harman The Uncommon Reactivity of Dihapto-Coordinated Nitrile, Ketone, and Alkene Ligands when Bound to a Powerful p-base Organometallics, 2006, 25, M.A. Todd, M. Grachen*, W.H. Myers, W.D. Harman Common Electrophilic Addition Reactions at the Phenol Ring: the Chemistry of TpW(NO)(PMe 3 )(η 2 -phenol) Organometallics, 2006, 25, May 31, K.C. Bassett, F. You, P.M. Graham, W.H. Myers, M. Sabat, W. Dean Harman Furan [3+2] Dipolar Cycloadditions Promoted by a π-basic Tungsten Metal Fragment Organometallics, 2006, 25, W.H. Myers, K.D. Welch, P.M. Graham, A.P. Keller*, M. Sabat, W.D. Harman Tungsten(0) and Rhenium(I) η 2 -Pyrrole Complexes: Dearomatization of Pyrroles and their Facile Isomerizations, Protonations, and Reductions Organometallics, 2005, 24, P.M. Graham, D.A. Delafuente, W. Liu, W.H. Myers, M. Sabat, W.D. Harman Facile Diels- Alder Reactions with Pyridines Promoted by Tungsten Journal of the American Chemical Society, 2005, 127, May 31, Curriculum Vitae William H. Myers p D.A.Delafuente, W.H.Myers, M. Sabat, W.D. Harman Tungsten(0) η 2 -Thiophene Complexes: Dearomatization of Thiophene and Its Facile Oxidation, Protonation, and Hydrogenation Organometallics, 2005; 24, May 31, M.T. Valohovic, W.H. Myers, and W.D. Harman Discrimination of Enantiofaces and Stereoselective Electrophilic Addition Reactions of η 2 -Pyrrole Complexes of Pentaammineosmium(II) Organometallics, 2002, 21, May 31, H. Chen, R. Caughey*, R. Liu, M. McMills, M. Rupp, W.H. Myers, W.D. Harman Novel Cyclization Reactions for η 2 -Furan Complexes, Tetrahedron, 2000, 56, May 31, H. Chen, R. Liu, W.H. Myers, and W.D. Harman, Dearomatization of Furan: Elementary Transformations of η 2 -Coordinated Furan Complexes of Pentaammineosmium(II), Journal of the American Chemical Society, 1998, 120, May 31, L.M. Hodges, J. Gonzales, J.I. Koontz*, W.H. Myers, and W.D. Harman, β-electrophilic Additions of Pentaammineosmium(II) η 2 -Pyrrole Complexes, Journal of Organic Chemistry, 1995, 60, J. Gonzales, J.I. Koontz*, L.M. Hodges, K.R. Nilsson*, L.K. Neely*, W.H. Myers, M. Sabat, and W.D. Harman, Osmium Promoted Dipolar Cycloadditions with Pyrroles: An Efficient, Stereospecific Synthesis of 7-Azanorbornanes, Journal of the American Chemical Society, 1995, 117, May 31, L.M. Hodges, J. Gonzales, J.I. Koontz*, W.H. Myers, and W.D. Harman, η 2 -Pyrrole Complexes as Synthons to Alkaloid Derivatives, Journal of Organic Chemistry, 1993, 58, May 31, W.H. Myers, J.I. Koontz*, and W.D. Harman, Tautomerizations, Protonations, and Electrophilic Additions of η 2 -Coordinated Pyrroles, Journal of the American Chemical Society, 1992, 114, May 31, W.H. Myers, M. Sabat, and W.D. Harman, Enamine Character of a 2,3-η 2 -Coordinated Pyrrole, Journal of the American Chemical Society, 1991, 113, before May 31, W.H. Myers, An Industrial Sabbatical, Journal of Chemical Education, 1984, 61, W.H. Myers, Olefin Conversion, U.S Patent #4,423,275, December 27, W.H. Myers, Instructors' Manual to Chemistry: A Systematic Approach, Oxford University Press, New York, W.H. Myers and W.M. Mooney, Jr., Student Study Guide to Chemistry: A Systematic Approach, Oxford University Press, New York, W.H. Myers and G.E. Ryschkewitsch, Exchange of Deuterium for Hydrogen during the Reaction of Dimethylamine-N-d-Borane with Halogenating Agents, Inorganic Chemistry, 1978, 17, D.L. DuBois, W.H. Myers, and D.W. Meek, Synthesis of Polytertiary Phosphines and Mixed Phosphorus-Sulphur and Mixed Phosphorus-Nitrogen Polydentate Ligands via Free Radical Catalysis, Journal of the Chemical Society (Dalton), 1975, W.H. Myers and G.E. Ryschkewitsch, Trends in the Reactivity of Mixed Phenyl-Methyl Phosphine-Boranes Towards Hydrogen Halides, Phosphorus, 1975, 5, M.A. Mathur, W.H. Myers, H.H. Sisler, and G.E. Ryschkewitsch, Methyldiphenylphosphine- Borane and Dimethylphenylphosphine-Borane, Inorganic Syntheses, 1974, 15, Curriculum Vitae William H. Myers p.7 5. W.H. Myers, G.E. Ryschkewitsch, M.A. Mathur, and R.W. King, Trends in the Proton Nuclear Magnetic Resonance Spectra of Some Amine-Haloboranes: Steric Effects, Inorganic Chemistry, 1975, 14, G.E. Ryschkewitsch and W.H. Myers, Borane Trihalide-Amine Adducts: Direct and Indirect Synthesis, Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1975, 5, W.H. Myers and G.E. Ryschkewitsch, Dimethylamine-Tribromoborane, Inorganic Syntheses, 1974, 15, A.P. Gaughan, Jr., B.L. Haymore, J.A. Ibers, W.H. Myers, T.E. Nappier, Jr., and D.W. Meek, An Extension of the Nitrosyl-Aryldiazo Analogy. The Structure of an Aryldiazo Group Coordinated to Rhodium in a Doubly Bent Fashion, Journal of the American Chemical Society, 1973, 95, W.H. Myers* and A.W. Cordes, The Crystal Structure of Dimethylselenium Dichloride, Research Reports in Chemistry, NSF-URPP, University of Arkansas, 1966, Professional Presentations (undergraduate co-presenters starred = *): 50. Enantio-enrichment of {TPW(NO)(PMe 3 )} dearomatizing agent , March 2014, 247 th National Meeting of the American Chemical Society, Dallas, TX (paper INOR-236) A.W. Lankenau*, J.A. Pienkos, W.D. Harman, W.H. Myers 49. Exploration of reactivity of a novel tungsten-bound 2H-pyrrolium , April 2013, 245th National Meeting of the American Chemical Society, New Orleans, LA (paper #ORGANOMET-458) N.W. West*, D.A. Iovan*, W.H. Myers, K.D. Welch, W.D. Harman. 48. Stereoselective additions to naphthalene and anthracene complexes of {TpW(NO)(PMe 3 )} , August, 2012, 244 th National Meeting of the American Chemical Society, Philadelphia, PA (paper INOR-332) L. Strausberg, M. Li, W.H. Myers, W.D. Harman. 47. Towards enantiomeric products from tungsten-mediated reactions , October 2011, 63rd Southeastern Regional Meeting of the American Chemical Society, Richmond, VA (paper # INOR- 565) W.H. Myers, D.A. Iovan*, N.W. West*, W.D
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